18,882 research outputs found
Suppression of superconductivity by Neel-type magnetic fluctuations in the iron pnictides
Motivated by recent experimental detection of Neel-type ()
magnetic fluctuations in some iron pnictides, we study the impact of competing
and spin fluctuations on the superconductivity of these
materials. We show that, counter-intuitively, even short-range, weak Neel
fluctuations strongly suppress the state, with the main effect arising
from a repulsive contribution to the pairing interaction, complemented
by low frequency inelastic scattering. Further increasing the strength of the
Neel fluctuations leads to a low- d-wave state, with a possible
intermediate phase. The results suggest that the absence of
superconductivity in a series of hole-doped pnictides is due to the combination
of short-range Neel fluctuations and pair-breaking impurity scattering, and
also that of optimally doped pnictides could be further increased if
residual fluctuations were reduced.Comment: revised version accepted for publication in PR
Enhancement of by disorder in underdoped iron pnictides
We analyze how disorder affects the transition temperature of the
superconducting state in the iron pnictides. The conventional wisdom is
that should rapidly decrease with increasing inter-band non-magnetic
impurity scattering, but we show that this behavior holds only in the overdoped
region of the phase diagram. In the underdoped regime, where superconductivity
emerges from a pre-existing magnetic state, disorder gives rise to two
competing effects: breaking of the Cooper pairs, which tends to reduce ,
and suppression of the itinerant magnetic order, which tends to bring
up. We show that for a wide range of parameters the second effect wins, leading
to an increase of with disorder in the coexistence state. Our results
explain several recent experimental findings and provide another evidence for
-pairing in the iron pnictides.Comment: 5 pages, 3 figures; revised version accepted in PRB-R
Superlens made of a metamaterial with extreme effective parameters
We propose a superlens formed by an ultra-dense array of crossed metallic
wires. It is demonstrated that due to the anomalous interaction between crossed
wires, the structured substrate is characterized by an anomalously high index
of refraction and supports strongly confined guided modes with very short
propagation wavelengths. It is theoretically proven that a planar slab of such
structured material makes a superlens that may compensate for the attenuation
introduced by free-space propagation and restore the subwavelength details of
the source. The bandwidth of the proposed device can be quite significant since
the response of the structured substrate is non-resonant. The theoretical
results are fully supported by numerical simulations.Comment: Accepted for publication in Phys. Rev. B (in press
Fate of the Bose insulator in the limit of strong localization and low Cooper-pair density in ultrathin films
A Bose insulator composed of a low density of strongly localized Cooper pairs develops at the two-dimensional superconductor to insulator transition (SIT) in a number of thin film systems. Investigations of ultrathin amorphous PbBi films far from the SIT described here provide evidence that the Bose insulator gives way to a second insulating phase with decreasing film thickness. At a critical film thickness dc the magnetoresistance changes sign from positive, as expected for boson transport, to negative, as expected for fermion transport, signs of local Cooper-pair phase coherence effects on transport vanish, and the transport activation energy exhibits a kink. Below dc pairing fluctuation effects remain visible in the high-temperature transport while the activation energy continues to rise. These features show that Cooper pairing persists and suggest that the localized unpaired electron states involved in transport are interspersed among regions of strongly localized Cooper pairs in this strongly localized, low Cooper-pair density phase
Collapse of the Cooper pair phase coherence length at a superconductor to insulator transition
We present investigations of the superconductor to insulator transition (SIT)
of uniform a-Bi films using a technique sensitive to Cooper pair phase
coherence. The films are perforated with a nanohoneycomb array of holes to form
a multiply connected geometry and subjected to a perpendicular magnetic field.
Film magnetoresistances on the superconducting side of the SIT oscillate with a
period dictated by the superconducting flux quantum and the areal hole density.
The oscillations disappear close to the SIT critical point to leave a
monotonically rising magnetoresistance that persists in the insulating phase.
These observations indicate that the Cooper pair phase coherence length, which
is infinite in the superconducting phase, collapses to a value less than the
interhole spacing at this SIT. This behavior is inconsistent with the gradual
reduction of the phase coherence length expected for a bosonic, phase
fluctuation driven SIT. This result starkly contrasts with previous
observations of oscillations persisting in the insulating phase of other films
implying that there must be at least two distinct classes of disorder tuned
SITs
Büchwald-Hartwig reaction applied to synthesis of new luminescent liquid crystal triarylamines derived from isoxazoles
© 2015 Taylor & Francis Group, LLC. The present work describes the synthesis and characterization of novel series of triarylamines isoxazoles (TAA) addressed to the organic photovoltaic materials. Diarylisoxazoles were synthesized by sequential [3+2] 1,3-dipolar cycloaddition reaction between arylnitrile oxides and selected arylalkenes followed by MnO2-oxidation. Isoxazoles were coupled to diarylamines by Büchwald-Hartwig reaction to afford desired compounds 6a-k. Some TAA display liquid-crystalline behaviour and UV-Vis absorption and fluorescence emission were analysed for all samples of TAA 6a-k
Technology adoption and the investment climate : firm-level evidence for Eastern Europe and Central Asia
The international diffusion of technology presents an opportunity for developing economies distant from the world technological frontier to reduce their income gap relative to advanced economies. It is therefore crucial to understand why, when faced with similar technological alternatives different firms in different countries choose to adopt different vintages of capital. This paper examines technology adoption across firms in Eastern Europe and Central Asia. The findings show that access to complementary inputs - managerial capacity, skilled labor, finance, and good infrastructure - and to international knowledge - through foreign direct investment or exports - is an important correlate of technology adoption. The link between market incentives and technology adoption is more nuanced. Although consumer pressure results in technology adoption, competitor pressure does not, suggesting that only firms with rents are able to adopt technology given substantial resource constraints. Privatized firms exhibit better technology adoption outcomes but only when a clear private owner with a profit incentive is present. Better governance is associated with technology adoption only in the countries that joined the European Union in 2004. Future increases in technology adoption by firms in the region will require complementary reforms of the investment climate.E-Business,Technology Industry,ICT Policy and Strategies,Microfinance,
Impacts of in vivo and in vitro exposures to tamoxifen: comparative effects on human cells and marine organisms
Tamoxifen (TAM) is a first generation-SERM administered for hormone receptor-positive (HER+) breast cancer in both pre- and post-menopausal patients and may undergo metabolic activation in organisms that share similar receptors and thus face comparable mechanisms of response. The present study aimed to assess whether environmental trace concentrations of TAM are bioavailable to the filter feeder M. galloprovincialis (100 ng L-1) and to the deposit feeder N. diversicolor (0.5, 10, 25 and 100 ng L-1) after 14 days of exposure. Behavioural impairment (burrowing kinetic), neurotoxicity (AChE activity), endocrine disruption by alkali-labile phosphate (ALP) content, oxidative stress (SOD, CAT, GPXs activities), biotransformation (GST activity), oxidative damage (LPO) and genotoxicity (DNA damage) were assessed. Moreover, this study also pertained to compare TAM cytotoxicity effects to mussels and targeted human (i.e. immortalized retinal pigment epithelium - RPE; and human transformed endothelial cells - HeLa) cell lines, in a range of concentrations from 0.5 ng L-1 to 50 μg L-1. In polychaetes N. diversicolor, TAM exerted remarkable oxidative stress and damage at the lowest concentration (0.5 ng L-1), whereas significant genotoxicity was reported at the highest exposure level (100 ng L-1). In mussels M. galloprovincialis, 100 ng L-1 TAM caused endocrine disruption in males, neurotoxicity, and an induction in GST activity and LPO byproducts in gills, corroborating in genotoxicity over the exposure days. Although cytotoxicity assays conducted with mussel haemocytes following in vivo exposure was not effective, in vitro exposure showed to be a feasible alternative, with comparable sensitivity to human cell line (HeLa).info:eu-repo/semantics/publishedVersio
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